Theory and Destination : The Diels–Alder reaction is an electrocyclic cycloaddition reaction were diene reacts with an alkene (dienophile) in presence of Lewis Acid to give unsaturated six-membered ring.The reaction incorporates [4+2]‑cycloaddition of 4 Ï€-electrons of the framed diene and 2 Ï€-electrons of the dienophi…
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MARCH’S ADVANCED ORGANIC CHEMISTRY 4th EDITION REACTIONS, MECHANISMS AND STRUCTURE 4th EDITION Michael B. Smith Professor of Chemistry Jerry March Professor of Chemistry WILEY-INTERSCIENCE A JOHN WILEY & SONS, INC., PUBLICATION By Editorial - Knowledge of organic chemistry continues to move ahead on many fronts. N…
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Theory and Defination : Dess-Martin oxidation is a selective mild oxidation synthesis for the conversion of primary and secondary alcohols into corresponding aldehydes and ketones.The main ingrediant used for this oxidation is Dess-Martin periodinane or DMP.It is named after Daniel Benjamin Dess and James Cullen Marti…
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Theory and Destination : DeMayo reaction is a photo chemical reaction in which the enol of a 1,3-di-ketone reacts with an alkene (or another species with a C=C bond) and the resulting cyclobutane ring undergoes a retro- aldol reaction to yield a 1,5-di ketone. General Reaction : Mechanism : A visible…
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